6/15/2023 0 Comments Endnote cuny library hunterThis review provides an overview of the chemistry of fluorinated porphyrinoids that are being used as a platform to create libraries of photo-active compounds for applications in medicine and materials. The remaining fluoro groups enhance the photo and oxidative stability of the dyes and can serve as spectroscopic signatures to characterize the compounds or in imaging applications using 19F NMR. Derivatives of all six of these core platforms can be efficiently and controllably made via mild nucleophilic aromatic substitution reactions using primary S, N, and O nucleophiles bearing a wide variety of functional groups. ![]() ![]() The perfluorophenylporphyrin is readily converted to the chlorin, bacteriochlorin, and isobacteriochlorin. We have focused on several widely available, commercially viable porphyrinoids as platforms: meso-perfluorophenylporphyrin, perfluorophthalocyanine, and meso-perfluorophenylcorrole. Thus, the application of core porphyrinoid platforms that can be rapidly and efficiently modified to evaluate new molecular architectures allows researchers to focus on the design concepts rather than the synthesis methods, and opens porphyrinoid chemistry to a broader scientific community. The synthesis of the porphyrinoid depends on the desired application, but the de novo synthesis often involves several steps, is time consuming, and results in low isolated yields. Most applications of these dyes require exocyclic moieties to improve solubility, target diseases, modulate photophysical properties, or direct the self-organization into architectures with desired photonic properties. Commercial applications include their use as phthalocyanine dyes in optical discs, porphyrins in photodynamic therapy, and as oxygen sensors. You may also choose to simply use an in-text citation in the caption (parenthetical or footnote, depending on your style guide), in which case you would include a full source citation in your Bibliography.Porphyrinoids are robust heterocyclic dyes studied extensively for their applications in medicine and as photonic materials because of their tunable photophysical properties, diverse means of modifying the periphery, and the ability to chelate most transition metals. If you include a full citation in the caption you do not need to include the source in your Bibliography. ![]() It is also a reference database storing, managing, and searching for bibliographic references in your private reference library. You may wish to also consult the library's guide on citing social media and digital images. Endnote is an online search tool that provides a way to search online biblographic databases and retrieve the references directly into EndNote. If you took the photo or created the image yourself, indicate that in the caption (e.g., "Photo by author"). For assistance in constructing credit lines for a variety of sources, consult the Chicago Manual of Style 4.102 (17th ed.). This is often referred to as a credit line. The University at Buffalo Libraries are providing EndNote citation management software to UBs academic community. If you are reproducing images that you did not take or create yourself, you will need to cite them according to your citation style. The images themselves may be placed within the text or collated together at the end (before the Bibliography/References/Works Cited).Įach image should be captioned with the label and number, and a brief title of the image. You'll need to create a List of Figures that appears in the preliminary pages, directly following the Table of Contents. The library's requirements do not specify a specific size or resolution for images, but we do require that images are labeled and numbered as figures in the text.
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